Bio-based flame retardants
Phytic acid, lignin, cellulose derivatives and other biomass-based systems for biopolymers such as PLA and for commodity plastics.
Flame retardancy of polymers & composites
Polymers are everywhere in buildings, vehicles, cables and batteries, and they burn. Our goal, as a scientific and industrial community, is to design halogen-free, bio-based and recyclable flame-retardant materials that slow fire growth and meet safety standards while staying compatible with a circular economy.
Illustrative curves showing the typical effect of a char-forming flame-retardant system: a lower, flatter heat release peak and less total heat. The heat release rate (HRR) peak is the main driver of fire growth.
The challenge
For decades, halogenated additives made polymers fire-safe cheaply. Regulation, health concerns and recycling targets now require a new generation of solutions.
Several brominated flame retardants are restricted as persistent organic pollutants, and REACH keeps adding substances (including boric acid) to its candidate list. Melamine, the basis of widely used nitrogen flame retardants, is now a substance of very high concern, and ECHA recommended it for REACH authorisation in 2025. We are developing effective alternatives that are safe by design, including melamine-free systems.
Recycled polymers and bio-based resins must reach the same fire classifications as virgin materials. A patented process developed at Materia Nova depolymerises PU and PIR foam waste into recycled polyols by catalytic glycolysis in reactive extrusion, a continuous route suited to industrial scale-up. New rigid foams containing 50 wt.% recycled polyol can then be flame-retarded with phosphorus-based and bio-based additives to meet building requirements.
Lithium-ion batteries, electric vehicles and composite structures bring new fire scenarios, from thermal runaway to fibre-reinforced parts in rail and aerospace.
Science
A burning polymer feeds itself: heat decomposes it into flammable gases, which burn and send heat back to the surface. Flame retardants break this cycle at different points.
Expertise
More than 20 years of research and industrial projects, from the molecule to the processed part and its fire test.
Phytic acid, lignin, cellulose derivatives and other biomass-based systems for biopolymers such as PLA and for commodity plastics.
Hydrated minerals, high-surface lime, calcium-based and organo-mineral systems for flame-retardant thermoplastics.
Flame-retardant thermoplastic and thermoset matrices for fibre-reinforced composites, for transport, construction and energy.
Rigid PU foams made with recycled polyols from a patented reactive-extrusion glycolysis process, flame-retarded to building standards.
Fire-resistant materials for battery housings and intrinsically flame-retarded solid polymer electrolytes to reduce fire risks in lithium-ion batteries, including UL 2596 torch-and-grit testing of enclosure materials.
Solvent-free routes to graft, synthesise or modify flame-retardant additives directly in continuous processes.
Fire testing expertise
Fire performance has to be measured, not assumed. Developing a flame-retardant material means working with the reaction-to-fire and electrical safety tests that industry uses to qualify it, from small-scale screening to the prediction of building classifications.
| Method | Standard | What it tells you |
|---|---|---|
| Mass loss cone calorimeter | ISO 17554 | Monitoring of heat release and mass loss under a controlled radiant heat flux |
| Limiting Oxygen Index (LOI) | ISO 4589-2 ASTM D2863 | Minimum oxygen concentration that supports candle-like combustion |
| UL 94 | UL 94 IEC 60695-11-10 | Fire classification of materials, vertical and horizontal (V-0, V-1, V-2, HB) |
| Single-flame source test | EN ISO 11925-2 | Vertical flammability (ignitability) of products exposed to a small flame |
| Glow wire test | IEC 60695-2-11/-12/-13 | Flammability of plastic materials used in electrical and electronic products and household appliances (GWFI, GWIT) |
| CTI | IEC 60112 | Electrical tracking resistance of insulating materials, a key electrical and fire safety parameter for electronics, household appliances and electrical / e-mobility applications |
| Smoke chamber | ASTM D2843 | Smoke opacity from the combustion or decomposition of plastic materials |
| SBI simulation | – | Prediction of Single Burning Item results and Euroclass from cone calorimeter data |
| UL 2596 coming soon | UL 2596 | Thermal runaway simulation on battery enclosure materials: combined high-temperature torch and grit-blast exposure |
About the author
Polymer chemist (PhD 2003, HDR 2016) with more than 20 years of research on the flame retardancy and fire behaviour of polymers and composites, bridging academic research and industrial innovation.
News & insights
Regulatory updates, notable publications and industry developments on flame-retardant materials, with our reading of what they mean in practice.
Contact
Material substitution, a failed fire test, a new regulation or a collaborative project proposal: let's talk about it.
flaoutid@hotmail.comProfiles